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JAMB Chemistry Past Questions 2014

10 questions from the JAMB 2014 Chemistry paper, with answers and explanations. Tap "Show answer" under each one when you are ready.

JAMB 2014Question 1 · Acids, Bases, and Salts
The basicity of is
  1. A.4
  2. B.1
  3. C.2
  4. D.3
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Answer: B. 1

Ethanoic acid has only one ionizable hydrogen (from the -COOH group), giving it a basicity of 1.

JAMB 2014Question 2 · Atomic Structure and Chemical Bonding
A mixture is different from a compound because
  1. A.the properties of a compound are those of its individual constituents while those of a mixture differ from its constituents
  2. B.a mixture is always homogeneous while a compound is not
  3. C.the constituent of a compound are chemically bound together while those of a mixture are not
  4. D.a mixture can be represented by a chemical formula while a compound cannot
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Answer: C. the constituent of a compound are chemically bound together while those of a mixture are not

In a compound, constituent elements are held together by chemical bonds in fixed proportions; in a mixture, constituents are simply combined physically and retain their individual properties.

JAMB 2014Question 3 · Chemistry of Non-metals and Gases
A gas X diffuses twice as fast as gas Y. if the relative molecular mass of X is 32, calculate the relative molecular mass of Y.
  1. A.128
  2. B.8
  3. C.16
  4. D.64
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Answer: A. 128

By Graham's law, rate is inversely proportional to . RateX/RateY = ; 2 = , so My = 4x32 = 128.

JAMB 2014Question 4 · Electrochemistry and Redox Reactions
The oxidizing agent in the reaction above is
  1. A.
  2. B.
  3. C.
  4. D.H (2) (g)
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Answer: C.

In the water-gas reaction, supplies which is reduced to (H goes from +1 to 0), making the oxidizing agent (carbon is oxidized to CO).

JAMB 2014Question 5 · Electrochemistry and Redox Reactions
In the electrolytic extraction of calcium from calcium chloride, the cathode is
  1. A.zinc
  2. B.graphite
  3. C.platinum
  4. D.iron
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Answer: D. iron

In the electrolytic extraction of calcium from molten calcium chloride, iron is commonly used as the cathode.

JAMB 2014Question 6 · Organic Chemistry
The general formula of haloalkanes where X represents the halide is
  1. A.C n n-1 X.
  2. B.C n n X.
  3. C.C n n+2 X
  4. D.C n n+1 X
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Answer: D. C n n+1 X

The general formula for haloalkanes is CnH2n+1X.

JAMB 2014Question 7 · Organic Chemistry
The process of converting starch to ethanol is
  1. A.cracking
  2. B.distillation
  3. C.fermentation
  4. D.oxidation
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Answer: C. fermentation

Fermentation, using enzymes (e.g. from yeast), converts starch (via glucose) into ethanol.

JAMB 2014Question 8 · Organic Chemistry
The process of converting linear alkanes to branched chain and cyclic hydrocarbons by heating in the presence of a catalyst to improve the quality of petrol is referred to as
  1. A.refining
  2. B.cracking
  3. C.reforming
  4. D.blending
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Answer: C. reforming

Reforming converts straight-chain alkanes into branched-chain and cyclic/aromatic hydrocarbons using a catalyst, improving petrol's octane rating.

JAMB 2014Question 9 · Physical Chemistry
The radio active radiation used in studying the arrangement of particles in giant organic molecules is
  1. A.- rays
  2. B.- particles
  3. C.X-rays
  4. D. - particles
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Answer: C. X-rays

X-rays are used to study the arrangement of particles/atoms in giant molecules through X-ray diffraction/crystallography.

JAMB 2014Question 10 · Physical Chemistry
In an equilibrium reaction, which of the following conditions indicates that maximum yield of the product will be obtained?
  1. A.Equilibrium constant is very large
  2. B.∆H - T∆S = O
  3. C.∆ H > T ∆ S
  4. D.Equilibrium constant is less than zero
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Answer: A. Equilibrium constant is very large

A very large equilibrium constant indicates the equilibrium lies strongly towards products, giving maximum yield.

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